Allenylidene Induced 1,2?Metalate Rearrangement of Indole?Boronates: Diastereoselective Access to Highly Substituted Indolines
نویسندگان
چکیده
A process to achieve 1,2-metalate rearrangements of indole boronate as a way access substituted indolines in high diastereoselectivities is presented. The reaction involves the generation Cu–allenylidene, which sufficiently electrophilic induce rearrangement. scope evaluated well further transformations product.
منابع مشابه
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202103108